Have a sit down with her and ask her what she thinks could help prevent this from happening again. Maybe some PTO to focus on school? Assigning her low-risk tasks for the time being? Have her calculations be double checked by a colleague, before they are finalized?
By not only addressing the problem with her, but also engaging her in finding the solution, you provide her with the opportunity to be open, transparent, and learn how to think in solutions rather than problems, which could be a very worthwhile investment that benefits both her and your business.
Your biggest hurdle is your mindset. Work with a coach to change that, and your (work)life will improve. You are telling yourself all these stories about why everything is so important and needs to happen right now. If you continue to do that, you’ll reach a point where your body will just shut off. It’s already giving you very clear warning signs, listen to those!